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Updated: Jun 20, 2026

Analyzing the Photo-oxidation of 2-propanol at Indoor Air Level Concentrations Using Field Asymmetric Ion Mobility Spectrometry
Published on: June 14, 2018
Infrared spectroscopy of ozone and hydrogen chloride aerosols
Chris Medcraft1, Evan G Robertson, Chris D Thompson
1School of Chemistry, Monash University, Victoria 3800, Australia.
Abstract:
Aerosols of ozone have been generated in a collisional cooling cell and observed over a small temperature range via FTIR spectroscopy, with the phase transition from the vapour taking place in the range 80-84 K. The condensed phase bands at 1038 cm(-1) (nu3) and 2105 cm(-1) (nu1+nu3) were assigned to the liquid phase. Aerosols were also generated from mixtures of ozone and HCl. In the presence of liquid ozone aerosols, evidence of solvated HCl was observed via a broad IR band 2795 cm(-1). Notably, production of a metastable, amorphous solid phase of HCl (exhibiting a narrow band at 2780 cm(-1)) was favoured to the extent that it could be generated in large excess over the crystalline orthorhombic form that usually dominates at 80 K.
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