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Related Concept Videos

Membrane Fluidity01:23

Membrane Fluidity

Cell membranes are composed of phospholipids, proteins, and carbohydrates loosely attached to one another through chemical interactions. Molecules are generally able to move about in the plane of the membrane, giving the membrane its flexible nature called fluidity. Two other features of the membrane contribute to membrane fluidity: the chemical structure of the phospholipids and the presence of cholesterol in the membrane.Fatty acids tails of phospholipids can be either saturated or...
Membrane Fluidity01:26

Membrane Fluidity

Membrane fluidity is explained by the fluid mosaic model of the cell membrane, which describes the plasma membrane structure as a mosaic of components—including phospholipids, cholesterol, proteins, and carbohydrates—that gives the membrane a fluid character.
Mosaic nature of the membrane
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Micelles

Micelle formation is an intricate process that hinges on the properties of amphiphilic or amphipathic molecules and the conditions of the system in which they are found. Amphiphilic molecules, which have both hydrophilic (water-attracting) and hydrophobic (water-repelling) parts, play a critical role in this process.In aqueous environments, these molecules arrange themselves such that their hydrophilic heads are turned towards the water phase, while their hydrophobic tails are oriented away...
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Colloids

Children at play often make suspensions such as mixtures of mud and water, flour and water, or a suspension of solid pigments in water known as tempera paint. These suspensions are heterogeneous mixtures composed of relatively large particles that are visible to the naked eye or can be seen with a magnifying glass. They are cloudy, and the suspended particles settle out after mixing. On the other hand, a solution is a homogeneous mixture in which no settling occurs and in which the dissolved...
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The Colloidal State

The formation of a colloidal system is exemplified by an aqueous solution containing Cl− ions is introduced to another containing Ag+ ions, resulting in the precipitation of solid AgCl as extremely tiny crystals. Instead of settling out as a filterable precipitate, these crystals remain suspended in the liquid, showcasing a colloidal system.A colloidal system involves colloidal particles within the approximate range of 1 to 1000 nm in at least one dimension, dispersed in a medium called the...

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Particle Templated Emulsification enables Microfluidic-Free Droplet Assays
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Published on: March 9, 2021

Morphological transition and emulsification failure in globular microemulsions.

N Shimokawa1, S Komura

  • 1Department of Physics, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan. shimokawa@chem.scphys.kyoto-u.ac.jp

The Journal of Chemical Physics
|September 11, 2009
PubMed
Summary

This study explores microemulsion condensation, detailing how surfactant properties influence droplet phases and emulsification failure. It maps phase transitions, revealing conditions for spherical-to-cylindrical shifts and oil phase separation.

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Published on: October 24, 2017

Area of Science:

  • Colloid and Surface Science
  • Materials Science
  • Physical Chemistry

Background:

  • Microemulsions are thermodynamically stable mixtures of oil, water, and surfactant.
  • Condensation transitions in microemulsions can lead to emulsification failure, forming a macroscopic oil phase.
  • Understanding these transitions is crucial for controlling microemulsion behavior.

Purpose of the Study:

  • To determine the phase transition lines between spherical and cylindrical droplet phases in oil-in-water microemulsions.
  • To map the phase boundary lines for emulsification failure.
  • To investigate the influence of surfactant monolayer properties on microemulsion phase behavior.

Main Methods:

  • Free energy approach to model microemulsion phase transitions.
  • Calculation of phase diagrams by varying surfactant monolayer properties (saddle-splay modulus, spontaneous curvature).
  • Analysis of droplet phase transitions and emulsification failure boundaries.

Main Results:

  • For negative saddle-splay modulus, spherical droplets coexist with an excess oil phase, potentially showing re-entrant transitions (sphere-cylinder-sphere).
  • For positive saddle-splay modulus, a direct transition from cylindrical droplets to phase separation occurs.
  • The sphere-to-cylinder transition line approaches the emulsification failure boundary with increasing saddle-splay modulus.

Conclusions:

  • Surfactant properties, specifically saddle-splay modulus and spontaneous curvature, dictate microemulsion phase behavior and emulsification failure.
  • The study provides a theoretical framework for predicting and controlling microemulsion phase transitions.
  • Re-entrant transitions are possible under specific surfactant conditions, highlighting complex phase dynamics.