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Microwave chemistry in silicon carbide reaction vials: separating thermal from nonthermal effects

David Obermayer1, Bernhard Gutmann, C Oliver Kappe

  • 1Christian Doppler Laboratory for Microwave Chemistry (CDLMC) and Institute of Chemistry, Karl-Franzens-University Graz, Heinrichstrasse 28, 8010 Graz, Austria.

Angewandte Chemie (International Ed. in English)
|September 29, 2009
PubMed
Abstract

No abstract available in PubMed .

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Sigmatropic rearrangements are a class of pericyclic reactions in which a σ bond migrates from one part of a π system to another. These are intramolecular rearrangements where the total number of σ and π bonds remain unchanged.
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in 1,5-hexadiene, referred to as...