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Lewis Acids and Bases02:16

Lewis Acids and Bases

This lesson delves into Lewis acids and bases in the context of the octet rule for electron-deficient compounds. Here, the concept is discussed, emphasizing the group 13 elements like boron or aluminium. Since group 13 elements possess three valence electrons, they form trivalent compounds with a sextet of electrons and a vacant orbital for the central atom. Consequently, these electron-deficient compounds accept electrons from other species to complete their octet in a chemical reaction. They...
Lewis Acids and Bases02:33

Lewis Acids and Bases

In 1923, G. N. Lewis proposed a generalized definition of acid-base behavior in which acids and bases are identified by their ability to accept or to donate a pair of electrons and form a coordinate covalent bond.
A coordinate covalent bond (or dative bond) occurs when one of the atoms in the bond provides both bonding electrons. For example, a coordinate covalent bond occurs when a water molecule combines with a hydrogen ion to form a hydronium ion. A coordinate covalent bond also results when...
Exceptions to the Octet Rule02:55

Exceptions to the Octet Rule

Many covalent molecules have central atoms that do not have eight electrons in their Lewis structures. These molecules fall into three categories:
Biot-Savart Law: Problem-Solving00:59

Biot-Savart Law: Problem-Solving

The magnitude and direction of a magnetic field created by a steady current can be calculated using the Biot-Savart law.
Consider a mobile phone battery bank as a source of steady current, which flows through the wire connected between the two. What is the magnitude of the magnetic field created by this current at a field point P?
To estimate the magnitude of the total magnetic field, we first consider a small current element of length dl, at a distance r from the field point. Now the following...
The Bohr Model02:18

The Bohr Model

Following the work of Ernest Rutherford and his colleagues in the early twentieth century, the picture of atoms consisting of tiny dense nuclei surrounded by lighter and even tinier electrons continually moving about the nucleus was well established. This picture was called the planetary model since it pictured the atom as a miniature “solar system” with the electrons orbiting the nucleus like planets orbiting the sun. The simplest atom is hydrogen, consisting of a single proton as the nucleus...
The Atomic Theory of Matter02:59

The Atomic Theory of Matter

The earliest recorded discussion of the basic structure of matter comes from ancient Greek philosophers. Leucippus and Democritus argued that all matter was composed of small, finite particles that they called atomos, meaning “indivisible.” Later, Aristotle and others came to the conclusion that matter consisted of various combinations of the four “elements” — fire, earth, air, and water — and could be infinitely divided. Interestingly, these philosophers thought about atoms and “elements” as...

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Related Experiment Video

Updated: Jun 19, 2026

Interactive and Visualized Online Experimentation System for Engineering Education and Research
08:35

Interactive and Visualized Online Experimentation System for Engineering Education and Research

Published on: November 24, 2021

Boron: elementary challenge for experimenters and theoreticians.

Barbara Albert1, Harald Hillebrecht

  • 1Eduard-Zintl-Institute of Inorganic and Physical Chemistry, Technische Universität Darmstadt, Petersenstrasse 18, 64287 Darmstadt, Germany. albert@ac.chemie.tu-darmstadt.de

Angewandte Chemie (International Ed. in English)
|October 16, 2009
PubMed
Summary

Solid-state boron chemistry remains challenging, but recent theoretical and experimental advances reveal new compound structures and properties. Further research is needed for synthesis, characterization, and understanding electronic structures of these materials.

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Area of Science:

  • Solid-state chemistry
  • Materials science
  • Inorganic chemistry

Background:

  • Over 200 years after its discovery, fundamental questions about boron's solid-state chemistry persist.
  • Recent theoretical and experimental studies, including high-pressure/high-temperature work, have illuminated new aspects of boron modifications.
  • Significant progress has been made in understanding reactions between boron and main group elements.

Purpose of the Study:

  • To review recent advancements in the solid-state chemistry of boron and its compounds.
  • To highlight key binary compounds and boride carbides with interesting properties.
  • To discuss the challenges and future directions in boron materials research.

Main Methods:

  • Theoretical calculations on the existence and stability of boron modifications.
  • High-pressure and high-temperature experimental investigations.
  • Analysis of structural and physical properties of newly synthesized boron compounds.

Main Results:

  • Excitement surrounds binary compounds like B(6)O, MgB(2), LiB(1-x), Na(3)B(20), and CaB(6).
  • Electron-precise boride carbides (e.g., Li(2)B(12)C(2)) and BeB(2)C(2) show promise.
  • Boron-rich compounds exhibit attractive physical properties for materials research, including hardness, superconductivity, and thermoelectricity.

Conclusions:

  • Linked polyhedra are key structural motifs in boron-rich main group compounds.
  • Major challenges include macroscopic synthesis, single-crystal growth, unambiguous structure determination, and understanding electronic properties.
  • Existing structural assignments for boron modifications require critical revision and discussion.