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Updated: Jun 19, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Water oxidation at a tetraruthenate core stabilized by polyoxometalate ligands: experimental and computational
Andrea Sartorel1, Pere Miró, Enrico Salvadori
1ITM-CNR and Department of Chemical Sciences, University of Padova, via F. Marzolo 1, 35131 Padova, Italy.
Abstract:
Converging UV-vis, EPR, rRaman, and DFT calculations highlight the evolution of [Ru(4)(H(2)O)(4)(mu-O)(4)(mu-OH)(2)(gamma-SiW(10)O(36))(2)](10-), 1, to high-valent intermediates. In analogy with the natural enzyme, five different oxidation states, generated from 1, have been found to power the catalytic cycle for water oxidation. A high electrophilic tetraruthenium(V)-hydroxo species is envisaged as the competent intermediate, undergoing nucleophilic attack by an external water molecule as a key step in the formation of a new O-O bond under catalytic conditions.
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