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Geometry dependence of the ring-opening E2 reaction in lactones

Xin Chen1, David A Walthall, John I Brauman

  • 1Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA.

The Journal of Physical Chemistry. A
|October 29, 2009
PubMed
Summary

This study investigated gas phase bimolecular elimination (E2) reactions in lactones. Geometric distortion significantly impacts E2 reactions in smaller rings, outweighing ring strain effects.

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