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Updated: Jun 19, 2026

A Simple and Efficient Protocol for the Catalytic Insertion Polymerization of Functional Norbornenes
Published on: February 27, 2017
Platinum-catalyzed nucleophilic addition of vinylsilanes at the beta-position
Katsukiyo Miura1, Gen Inoue, Hisashi Sasagawa
1Department of Applied Chemistry, Graduate School of Science and Engineering, Saitama University, Sakura-ku, Saitama 338-8570, Japan. kmiura@apc.saitama-u.ac.jp
Abstract:
In the presence of catalytic amounts of PtCl(2) and metal iodides, beta-substituted vinylsilanes reacted with aldehydes at the beta-position to give allyl silyl ethers. The Pt-catalyzed addition to aromatic aldehydes proceeded efficiently in the presence of LiI. The combined use of PtCl(2) and MnI(2) was found to be effective in addition to aliphatic aldehydes.
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