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Related Concept Videos

NMR Spectrometers: Radiofrequency Pulses and Pulse Sequences01:17

NMR Spectrometers: Radiofrequency Pulses and Pulse Sequences

A pulse is a short burst of radio waves distributed over a range of frequencies that simultaneously excites all the nuclei in the sample. Upon passing a radio frequency pulse along the x-axis, the nuclei absorb energy corresponding to their Larmor frequencies and achieve resonance. This shifts the net magnetization vector from the z-axis toward the transverse plane. This angle of rotation of the magnetization vector, or the flip angle, is proportional to the duration and intensity of the pulse.

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Related Experiment Video

Updated: Jun 19, 2026

Low-cost Custom Fabrication and Mode-locked Operation of an All-normal-dispersion Femtosecond Fiber Laser for Multiphoton Microscopy
08:48

Low-cost Custom Fabrication and Mode-locked Operation of an All-normal-dispersion Femtosecond Fiber Laser for Multiphoton Microscopy

Published on: November 22, 2019

Frequency-modulation spectroscopy with transform-limited nanosecond laser pulses.

E E Eyler, S Gangopadhyay, N Melikechi

    Optics Letters
    |October 30, 2009
    PubMed
    Summary
    This summary is machine-generated.

    We achieved high-quality Frequency Modulation (FM) spectra using nanosecond laser pulses. This technique offers superior spectral resolution and sensitivity, enabling new far-ultraviolet spectroscopic observations.

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    A Multimodal Wide-Field Fourier-Transform Raman Microscope
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    Published on: December 30, 2025

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    Low-cost Custom Fabrication and Mode-locked Operation of an All-normal-dispersion Femtosecond Fiber Laser for Multiphoton Microscopy
    08:48

    Low-cost Custom Fabrication and Mode-locked Operation of an All-normal-dispersion Femtosecond Fiber Laser for Multiphoton Microscopy

    Published on: November 22, 2019

    A Multimodal Wide-Field Fourier-Transform Raman Microscope
    06:48

    A Multimodal Wide-Field Fourier-Transform Raman Microscope

    Published on: December 30, 2025

    Area of Science:

    • Atomic and Molecular Spectroscopy
    • Laser Physics
    • Ultrafast Optics

    Background:

    • Frequency Modulation (FM) spectroscopy is a sensitive technique for detecting atomic and molecular species.
    • Traditional FM spectroscopy often requires continuous-wave (CW) lasers, limiting its application with pulsed systems.
    • Achieving high spectral resolution and sensitivity with pulsed lasers presents a significant challenge.

    Purpose of the Study:

    • To demonstrate high-quality FM spectra generation using nanosecond laser pulses.
    • To adapt FM spectroscopy for pulsed laser amplification and nonlinear frequency conversion.
    • To explore the application of this technique for novel spectroscopic observations in the ultraviolet region.

    Main Methods:

    • Generation of transform-limited pulses with FM sidebands via pulsed amplification of a phase-modulated CW laser.
    • Nonlinear optical mixing to shift the laser pulses into the ultraviolet (UV) spectral region.
    • Application of the developed technique to iodine (I2) spectroscopy and far-UV transition observation.

    Main Results:

    • Successful generation of high-quality FM spectra using nanosecond laser pulses.
    • Observation of an I2 spectrum with high spectral resolution (~0.001 cm(-1)).
    • First reported observation of a far-UV transition at 214.5 nm using FM spectroscopy with pulsed lasers.

    Conclusions:

    • The developed pulsed FM spectroscopy method provides excellent spectral resolution and optical phase definition.
    • The technique offers advantages of a smaller, easily detectable modulation frequency (~500 MHz) and high absorption sensitivity (~10(-4)).
    • This method is promising for future spectroscopic studies, particularly in the challenging far-UV region, with potential for further sensitivity improvements.