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Related Concept Videos

Temperature Dependence on Reaction Rate02:55

Temperature Dependence on Reaction Rate

The Collision Theory
Atoms, molecules, or ions must collide before they can react with each other. Atoms must be close together to form chemical bonds. This premise is the basis for a theory that explains many observations regarding chemical kinetics, including factors affecting reaction rates.
The collision theory is based on the postulates that (i) the reaction rate is proportional to the rate of reactant collisions, (ii) the reacting species collide in an orientation allowing contact between...
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The Arrhenius equation,
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When a current moves through any conductor, the conductor causes some level of difficulty for the current to flow. The measure of that difficulty is known as the resistance of the material and is represented by R. Every material has its own resistance. In the case of conductors, heat is emitted whenever a current passes through them. Resistance depends on the resistivity of the material. Resistivity is a characteristic of the material used to fabricate electrical components, whereas the...
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The Arrhenius equation relates the activation energy and the rate constant, k, for chemical reactions. In the Arrhenius equation, k = Ae−Ea/RT, R is the ideal gas constant, which has a value of 8.314 J/mol·K, T is the temperature on the kelvin scale, Ea is the activation energy in J/mole, e is the constant 2.7183, and A is a constant called the frequency factor, which is related to the frequency of collisions and the orientation of the reacting molecules.
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Effects of Temperature on Free Energy02:11

Effects of Temperature on Free Energy

The spontaneity of a process depends upon the temperature of the system. Phase transitions, for example, will proceed spontaneously in one direction or the other depending upon the temperature of the substance in question. Likewise, some chemical reactions can also exhibit temperature-dependent spontaneities. To illustrate this concept, the equation relating free energy change to the enthalpy and entropy changes for the process is considered:

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A Rapid Laser Probing Method Facilitates the Non-invasive and Contact-free Determination of Leaf Thermal Properties
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THE TEMPERATURE COEFFICIENT OF PHOTOSYNTHESIS.

W J Osterhout1, A R Haas

  • 1Laboratory of Plant Physiology, Harvard University, Cambridge.

The Journal of General Physiology
|October 30, 2009
PubMed
Summary
This summary is machine-generated.

The temperature coefficient of photosynthesis in Ulva, a type of seaweed, was found to be 1.81 between 17 and 27 degrees C. This suggests photosynthesis may involve two distinct reaction stages with different temperature sensitivities.

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Area of Science:

  • * Marine biology
  • * Photosynthesis research
  • * Plant physiology

Background:

  • * Photosynthesis is crucial for marine ecosystems.
  • * Understanding temperature effects on photosynthesis is key for predicting algal productivity.
  • * Ulva species are common seaweeds with significant ecological roles.

Purpose of the Study:

  • * To determine the temperature coefficient of photosynthesis in Ulva.
  • * To investigate the underlying reaction mechanisms influencing this coefficient.

Main Methods:

  • * Measurement of photosynthetic rates in Ulva samples.
  • * Controlled temperature experiments within the range of 17 to 27 degrees C.
  • * Analysis of temperature-dependent kinetic parameters.

Main Results:

  • * The overall temperature coefficient for photosynthesis in Ulva was calculated to be 1.81.
  • * This value was observed within a temperature range of 17 to 27 degrees C.

Conclusions:

  • * The calculated temperature coefficient suggests a complex photosynthetic process in Ulva.
  • * The findings support a model involving a light-dependent reaction with lower temperature sensitivity.
  • * An subsequent, ordinary reaction with higher temperature sensitivity likely contributes to the overall rate.