Related Experiment Video
Updated: Jun 19, 2026

HKUST-1 as a Heterogeneous Catalyst for the Synthesis of Vanillin
Published on: July 23, 2016
Tetranuclear vanadium complex, (VO)(4)(hpic)(4): a recyclable catalyst for oxidation of benzyl alcohols with
Shintaro Kodama1, Yukihiro Ueta, Jun Yoshida
1Department of Applied Chemistry, Graduate School of Engineering, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531, Japan.
Abstract:
Vanadium(iv) complexes bearing 3-hydroxypicolinic acid (H(2)hpic) as ligands, VO(Hhpic)(2) (1) and the cyclic tetramer (VO)(4)(hpic)(4) (2), have excellent catalytic ability for the oxidation of a variety of primary and secondary benzyl alcohols with molecular oxygen in acetonitrile or protic solvents such as ethanol and water, affording the corresponding aldehydes and ketones, respectively. Construction of multi-nuclear complexes by the selection of ligands attains higher turnover numbers and recycling of the catalyst.
More Related Videos
10:10Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
Published on: July 28, 2018
10:51The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Related Concept Videos
Radical Oxidation of Allylic and Benzylic Alcohols
Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation
Oxidation of Alkenes: Syn Dihydroxylation with Potassium Permanganate
Reactions at the Benzylic Position: Oxidation and Reduction
Oxidation of Alkenes: Syn Dihydroxylation with Osmium Tetraoxide
Benzene to 1,4-Cyclohexadiene: Birch Reduction Mechanism