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Updated: Jun 19, 2026

Catalytic Reactions at Amine-Stabilized and Ligand-Free Platinum Nanoparticles Supported on Titania During Hydrogenation of Alkenes and Aldehydes
Published on: June 24, 2022
Silica- and polymer-supported platinum(II) polypyridyl complexes: synthesis and application in photosensitized
Ke Feng1, Ming-Li Peng, Deng-Hui Wang
1Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, the Chinese Academy of Sciences, Beijing, 100190, PR China.
Abstract:
Square-planar polypyridine platinum(II) complexes have been introduced into a silica/polymer matrix by covalent ligand modification. The photophysical properties of the supported matrices are well retained as their model complexes, and the quantum yields for singlet oxygen ((1)O(2)) generation are comparable with that of TPP (tetraphenylporphyrin) under similar conditions. A preliminary application in photosensitized oxidation indicates the silica/polymer-supported matrices are promising, which can be reused without loss of reactivity by a simple filtration. Moreover, the polymer-supported matrix exhibits excellent compatibility in various solvents.
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