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From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
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Mesophases in nearly 2D room-temperature ionic liquids

N Manini1, M Cesaratto, M G Del Pópolo

  • 1European Theoretical Spectroscopy Facility and Dipartimento di Fisica, Universita di Milano, Via Celoria 16, 20133 Milan, Italy.

The Journal of Physical Chemistry. B
|November 6, 2009
PubMed
Summary

Computer simulations show that nanometric films of long-chain room-temperature ionic liquids (RTILs) form mesophases under high pressure. This 2D confinement and long alkyl chains are essential for mesophase formation, impacting lubricant properties.

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