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Updated: Jun 18, 2026

06:42
Measuring Phosphorus Release in Laboratory Microcosms for Water Quality Assessment
Published on: July 22, 2019
[Soil phosphorus form and fractionation scheme: a review]
1Key Laboratory of Ecological Restoration, Chengdu Institute of Biology, Chinese Academy of Sciences, Chengdu 610041, China. zhanglin@cib.ac.cn
Ying Yong Sheng Tai Xue Bao = the Journal of Applied Ecology
|November 11, 2009
Summary
Understanding soil phosphorus is vital for sustainable agriculture. This review examines phosphorus forms and fractionation methods, focusing on the widely used Hedley method and its modification, the Tiessen method, for assessing phosphorus availability and dynamics.
Area of Science:
- Agricultural Science
- Soil Science
- Environmental Science
Background:
- Phosphorus is an essential plant nutrient crucial for sustainable agriculture and ecosystem balance.
- Understanding soil phosphorus forms, transformations, and availability is critical for managing soil phosphorus supply and losses.
Purpose of the Study:
- To review recent research on soil inorganic and organic phosphorus forms.
- To evaluate various soil phosphorus fractionation schemes and their limitations.
- To discuss the Hedley method and its modification, the Tiessen method, in detail.
Main Methods:
- Review of recent scientific literature on soil phosphorus.
- Analysis of established phosphorus fractionation schemes, including the Hedley method.
- Discussion of modifications and applications of the Hedley method, such as the Tiessen method.
Main Results:
- The Hedley method is a widely adopted scheme for fractionating soil phosphorus, encompassing both organic and inorganic forms.
- Fractionation methods are essential for understanding phosphorus bioavailability and dynamics in soils.
- The Tiessen method offers a modification to the Hedley method, enhancing its applicability.
Conclusions:
- Appropriate soil phosphorus fractionation schemes are critical for effective soil management.
- The Hedley method and its modifications provide valuable insights into soil phosphorus dynamics and availability.
- Further research and application of these methods can support sustainable agricultural practices and ecosystem health.
Related Concept Videos
The Phosphorus Cycle
Unlike carbon, water, and nitrogen, phosphorus is not present in the atmosphere as a gas. Instead, most phosphorus in the ecosystem exists as compounds, such as phosphate ions (PO43-), found in soil, water, sediment and rocks. Phosphorus is often a limiting nutrient (i.e., in short supply). Consequently, phosphorus is added to most agricultural fertilizers, which can cause environmental problems related to runoff in aquatic ecosystems.
Factors Affecting Solubility
Compared with pure water, the solubility of an ionic compound is less in aqueous solutions containing a common ion (one also produced by dissolution of the ionic compound). This is an example of a phenomenon known as the common ion effect, which is a consequence of the law of mass action that may be explained using Le Chȃtelier’s principle. Consider the dissolution of silver iodide:

