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Molecular Entanglement and Electrospinnability of Biopolymers
Published on: September 3, 2014
Development of highly-transparent protein/starch-based bioplastics
J Gonzalez-Gutierrez1, P Partal, M Garcia-Morales
1Departamento de Ingeniería Química, Facultad de Ciencias Experimentales, Campus El Carmen, Universidad de Huelva, 21071 Huelva, Spain.
Bioresource Technology
|November 11, 2009
Summary
Albumen and starch bioplastics offer a biodegradable alternative to oil-based plastics. Thermo-mechanical processing yields transparent, strong materials suitable for packaging.
Area of Science:
- Materials Science
- Polymer Science
- Biotechnology
Background:
- The plastics industry seeks cost-competitive, sustainable alternatives to petroleum-derived polymers.
- Biomass-derived materials, such as starch and albumen, present a promising renewable resource.
- Developing efficient processing methods is crucial for creating viable bioplastics.
Purpose of the Study:
- To investigate the feasibility of incorporating starch (corn and potato) into albumen/glycerol formulations for bioplastic production.
- To evaluate the effects of varying starch concentrations (0-30 wt.%) and processing methods (thermo-plastic vs. thermo-mechanical) on material properties.
- To assess the potential of albumen/starch bioplastics as a biodegradable alternative for the plastics industry.
Main Methods:
- Preparation of albumen/starch-based bioplastics with varying starch content (0-30 wt.%).
- Utilized thermo-plastic and thermo-mechanical processing techniques.
- Characterization using transmittance measurements, Differential Scanning Calorimetry (DSC), Dynamic Mechanical Thermal Analysis (DMTA), and tensile testing.
Main Results:
- Starch concentration significantly influenced the optical and tensile properties of the bioplastics.
- Dynamic Mechanical Thermal Analysis (DMTA) at low deformation showed minimal sensitivity to starch addition.
- Thermo-mechanical processing resulted in transparent albumen/starch materials.
- Materials processed via thermo-mechanical methods exhibited tensile strength comparable to commodity plastics at low deformation.
Conclusions:
- Albumen/starch bioplastics can be cost-effectively produced using thermo-mechanical processing.
- These bioplastics demonstrate tunable optical and mechanical properties based on starch content.
- Albumen-based biopolymers show potential as a biodegradable substitute for conventional oil-derived plastics in applications like transparent packaging.
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