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Asymmetric construction of rings A-D of daphnicyclidin-type alkaloids
Travis B Dunn1, J Michael Ellis, Christiane C Kofink
1Department of Chemistry, 1102 Natural Sciences II, University of California, Irvine, California 92697-2025, USA.
Abstract:
The aza-Cope-Mannich reaction and ring-closing metathesis are key steps in the assembly of intermediates containing rings A-D of Daphniphyllum alkaloids of the daphnicyclidin type such as daphnipaxinin and oldhamine A.
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