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Updated: Jun 18, 2026

Chemiluminescence-based Assays for Detection of Nitric Oxide and its Derivatives from Autoxidation and Nitrosated Compounds
Published on: February 16, 2022
Low cost-sensors as a real alternative to on-line nitrogen analysers in continuous systems
1Department Enginyeria Química, Universitat de València, Doctor Moliner, 50, Burjassot, 46100 València, Spain. m.victoria.ruano@uv.es
Abstract:
This paper is focused on the evaluation of the applicability of low-cost sensors (pH and ORP) versus nutrient analysers for controlling biological nitrogen removal in WWTPs. A nutrient removal pilot plant located in Carraixet WWTP (Valencia, Spain) that is equipped with a significant number of nutrient analysers and low-cost sensors was used. The relations between reliable, cheap on-line sensors such as pH and ORP (located in anaerobic, anoxic and aerobic zones) and the nitrification/denitrification processes are provided. The nitrification process can be evaluated by measuring the pH difference between the first and last aerobic zones. The denitrification process can be evaluated by measuring the pH difference between the first and last anoxic zones and the ORP in the last anoxic zone. Furthermore, when WWTPs include an anaerobic reactor, the ORP in the anaerobic zone can also be used. With all these factors in mind, these sensors give valuable information for applying advanced control systems such as fuzzy logic-based controllers. Also, low-cost sensors involve lower investment, maintenance and operational costs and lower energy consumption derived from aeration and pumping than nutrient analysers. Thus, low-cost sensors can be successfully used as an attractive alternative to nutrient analysers to control biological nitrogen removal in WWTPs.
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