The 1,4-phenylenediisocyanide dimer: gas-phase properties and insights into organic self-assembled monolayers

Ryan P Steele1, Robert A Distasio, Martin Head-Gordon

  • 1Department of Chemistry, University of California-Berkeley, Berkeley, CA 94720, USA.

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Introduction
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Simple aryl halides do not react with nucleophiles under normal conditions. However, the reaction can proceed under drastic conditions involving high temperatures and high pressure to give the substituted products. For example, chlorobenzene is converted to phenol using aqueous sodium hydroxide at 350 °C under high pressure by the Dow process. The reaction follows an elimination-addition mechanism involving a benzyne intermediate. Here, the chloride ion is eliminated to generate the benzyne...
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π Molecular Orbitals of 1,3-Butadiene

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Introduction
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Characteristics and Nomenclature of Homopolymers

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