The fabrication of vanadium-doped ZnO piezoelectric nanofiber by electrospinning
1Key Laboratory of Low Dimensional Materials and Application Technology of Ministry of Education, and Faculty of Materials, Optoelectronics and Physics, Xiangtan University, Xiangtan, Hunan 411105, People's Republic of China.
Abstract:
Zn(1-x)V(x)O (x = 0.015, 0.02, 0.025, 0.03, V-ZnO) nanofibers were synthesized by electrospinning, and a butterfly-shaped piezoelectric response was measured by scanning force microscopy. The diameters of V-ZnO nanofibers with hexagonal wurtzite phase are in the range of 50-300 nm. The large piezoelectric coefficient d(33) of 121 pm V(-1) was obtained and the high piezoelectric property may be attributed to the switchable spontaneous polarization induced by V dopants and the easier rotation of V-O bonds under an electric field. The result shows that the V-ZnO nanofiber is a promising candidate for nanoscale piezoelectric devices.


