Partial ion yield spectroscopy around the Cl 2p and C 1s ionization thresholds in CF3Cl

We present a partial ion yield experiment on freon 13, CF(3)Cl, excited in the vicinity of the C 1s and Cl 2p ionization thresholds. We have collected a large amount of cationic fragments and a few anionic fragments at both edges. We have observed a strong intensity dependence of Rydberg transitions with ion fragment size for the CF(n)Cl(+) and CF(n)(+)/F(+) (n=0-3) series at both the Cl 2p and C 1s ionization edges. Selectivity in the fragmentation processes involving the C-Cl and C-F bonds are highlighted by the intensities of the C 1s to lowest unoccupied molecular orbital (LUMO) and LUMO+1 transitions measured on the CF(n)Cl(+) and CF(n)(+) yields. Equally, by comparison with their cation counterpart, we discuss possible bond-length dependence for the anion formation at the carbon 1s edge.