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Effect of Zn doping on improving crystal quality and thermoelectric properties of borosilicides

Takao Mori1, David Berthebaud, Toshiyuki Nishimura

  • 1National Institute for Materials Science (NIMS), Materials Nanoarchitechtonics Center (MANA), Namiki 1-1, Tsukuba, 305-0044, Japan. MORI.Takao@nims.go.jp

Dalton Transactions (Cambridge, England : 2003)
|January 13, 2010
PubMed

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Schottky defects arise when some lattice points in a crystal, such as those in NaCl, remain unoccupied, creating lattice vacancies without disturbing the overall electrical neutrality of the crystal. This defect is common in ionic crystals where the positive and negative ions are similar in size, as seen in sodium chloride and cesium chloride. The presence of Schottky defects enables the crystal to conduct electricity to a small extent through an ionic mechanism. Electric fields cause nearby...