Related Experiment Video
Updated: Jun 17, 2026

08:52
Near-Infrared Temperature Measurement Technique for Water Surrounding an Induction-heated Small Magnetic Sphere
Published on: April 30, 2018
On temperature determinations from nonresolved spectra
Applied Optics
|January 14, 2010
Summary
Interpreting film spectrograms from low-intensity sources requires careful densitometry. This study reveals that temperature measurements are most accurate away from prominent band heads, minimizing spectral line spread function effects.
Area of Science:
- Astrophysics
- Spectroscopy
- Photographic Spectroscopy
Background:
- Low-intensity astronomical sources often yield film spectrograms with large, overlapping spectral lines (nonresolved case).
- Accurate interpretation of densitometer scans from these photographic spectra is crucial for determining source temperatures.
- Existing methods may be affected by the characteristics of spectral line images and the densitometer's line spread function.
Purpose of the Study:
- To investigate the impact of combined line spread functions and image sizes on densitometer scan outputs for nonresolved film spectra.
- To apply these findings to the determination of spectroscopic temperatures for the CN violet system.
- To identify optimal spectral regions for accurate temperature measurements from photographic spectra.
Main Methods:
- Simulating densitometer scans of nonresolved film spectra using various assumed line spread functions and image sizes.
- Analyzing the resulting scan data to quantify the effects of these parameters.
- Applying the analysis to spectroscopic temperature determination of the CN violet system.
Main Results:
- Different line spread functions and image sizes significantly alter densitometer scan outputs for nonresolved spectra.
- The presence of prominent band heads introduces substantial distortions in the spectral line profiles.
- Spectroscopic temperature determinations are demonstrably affected by these instrumental and spectral features.
Conclusions:
- Accurate spectroscopic temperature determination from nonresolved film spectra necessitates accounting for line spread function effects.
- Densitometry should be performed in spectral regions with minimized line spread function influence, typically away from band heads.
- This research highlights critical considerations for analyzing photographic spectra of low-intensity sources.
More Related Videos
Related Concept Videos
Atomic Spectroscopy: Effects of Temperature
Atomization, converting samples into gas-phase atoms and ions, is essential for atomic spectroscopy. The flame temperature required for atomization affects the efficiency of the atomic spectroscopic methods by increasing the atomization efficiency and the relative population of the excited and ground states.
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature from...
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature from...
¹H NMR of Conformationally Flexible Molecules: Variable-Temperature NMR
The axial and equatorial protons in cyclohexane can be distinguished by performing a variable-temperature NMR experiment. In this process, except for one proton, the remaining eleven protons are replaced by deuterium. The deuterium substitution avoids the possible peak splitting caused by the spin-spin coupling between the adjacent protons. The remaining proton flips between the axial and equatorial positions.
Spectrophotometry: Introduction
Spectrophotometry is the quantitative measurement of the absorption, reflection, diffraction, or transmission of electromagnetic radiation through a material as a function of the intensity and wavelength of the radiation. A spectrophotometer is a device used to measure the change in the radiation intensity caused by its interaction with the material.
The essential components of a spectrophotometer include a source of electromagnetic radiation, a slot for placing a material to be analyzed, and a...
The essential components of a spectrophotometer include a source of electromagnetic radiation, a slot for placing a material to be analyzed, and a...
Temperature Measurement Sites
A thermometer measures body temperature. The common sites for measuring body temperature are the oral cavity, axillary region, temporal artery, and skin surface, such as the forehead, abdomen, and axilla. True core body temperature is assessed in the rectum, tympanic membrane, pulmonary artery, esophagus, and urinary bladder.
Oral: When assessing oral temperature, the thermometer tip should be placed under the tongue in the posterior sublingual pocket. It offers accurate readings and can be...
Oral: When assessing oral temperature, the thermometer tip should be placed under the tongue in the posterior sublingual pocket. It offers accurate readings and can be...
Flame Photometry: Overview
Flame photometry, also known as flame emission spectrometry, is a technique used for the qualitative and quantitative analysis of elements present in a sample using a flame as the source of excitation energy. The concept of flame photometry was realized in the early 1860s by Kirchhoff and Bunsen, who discovered that specific elements emit characteristic radiation when excited in flames. The first instrument developed for this purpose was used to measure sodium (Na) in plant ash using a Bunsen...
UV–Vis Spectrometers
The absorbance of UV and visible (UV–visible) radiations is measured using a UV–visible spectrophotometer. Deuterium lamps, which emit UV radiation, and tungsten lamps, which produce radiation in the visible region, are used as light sources in UV–visible spectrophotometers. A monochromator or prism is used for diffraction grating, i.e., to split the incoming radiation into different wavelengths. A system of slits is used to focus the desired wavelength on the sample cell. Samples for...

