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Related Concept Videos

Atomic Spectroscopy: Effects of Temperature01:27

Atomic Spectroscopy: Effects of Temperature

Atomization, converting samples into gas-phase atoms and ions, is essential for atomic spectroscopy. The flame temperature required for atomization affects the efficiency of the atomic spectroscopic methods by increasing the atomization efficiency and the relative population of the excited and ground states.
At thermal equilibrium, the relative populations of excited and ground state atoms can be estimated using the Maxwell–Boltzmann distribution. For example, an increase in temperature from...
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The axial and equatorial protons in cyclohexane can be distinguished by performing a variable-temperature NMR experiment. In this process, except for one proton, the remaining eleven protons are replaced by deuterium. The deuterium substitution avoids the possible peak splitting caused by the spin-spin coupling between the adjacent protons. The remaining proton flips between the axial and equatorial positions.
Spectrophotometry: Introduction01:16

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Near-Infrared Temperature Measurement Technique for Water Surrounding an Induction-heated Small Magnetic Sphere
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Published on: April 30, 2018

On temperature determinations from nonresolved spectra.

R Watson, W G Planet, C C Pitts

    Applied Optics
    |January 14, 2010
    PubMed
    Summary
    This summary is machine-generated.

    Interpreting film spectrograms from low-intensity sources requires careful densitometry. This study reveals that temperature measurements are most accurate away from prominent band heads, minimizing spectral line spread function effects.

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    Area of Science:

    • Astrophysics
    • Spectroscopy
    • Photographic Spectroscopy

    Background:

    • Low-intensity astronomical sources often yield film spectrograms with large, overlapping spectral lines (nonresolved case).
    • Accurate interpretation of densitometer scans from these photographic spectra is crucial for determining source temperatures.
    • Existing methods may be affected by the characteristics of spectral line images and the densitometer's line spread function.

    Purpose of the Study:

    • To investigate the impact of combined line spread functions and image sizes on densitometer scan outputs for nonresolved film spectra.
    • To apply these findings to the determination of spectroscopic temperatures for the CN violet system.
    • To identify optimal spectral regions for accurate temperature measurements from photographic spectra.

    Main Methods:

    • Simulating densitometer scans of nonresolved film spectra using various assumed line spread functions and image sizes.
    • Analyzing the resulting scan data to quantify the effects of these parameters.
    • Applying the analysis to spectroscopic temperature determination of the CN violet system.

    Main Results:

    • Different line spread functions and image sizes significantly alter densitometer scan outputs for nonresolved spectra.
    • The presence of prominent band heads introduces substantial distortions in the spectral line profiles.
    • Spectroscopic temperature determinations are demonstrably affected by these instrumental and spectral features.

    Conclusions:

    • Accurate spectroscopic temperature determination from nonresolved film spectra necessitates accounting for line spread function effects.
    • Densitometry should be performed in spectral regions with minimized line spread function influence, typically away from band heads.
    • This research highlights critical considerations for analyzing photographic spectra of low-intensity sources.