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Transition-state stabilization by a secondary substrate-ligand interaction: a new design principle for highly

Tomás Smejkal1, Denis Gribkov, Jens Geier

  • 1Institut für Organische Chemie und Biochemie, Freiburg Institute for Advanced Studies (FRIAS), Albert-Ludwigs-Universität Freiburg, Albertstrasse 21, 79104 Freiburg, Germany.

Chemistry (Weinheim an Der Bergstrasse, Germany)
|January 16, 2010
PubMed
Summary

Researchers designed novel phosphane ligands for regioselective hydroformylation of unsaturated carboxylic acids. These catalysts demonstrated excellent activity and selectivity, offering insights into supramolecular interactions for improved catalytic systems.

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