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Atomic Absorption Spectroscopy: Atomization Methods

Atomic Absorption Spectroscopy (AAS) atomizes samples through flame atomization or electrothermal atomization. Flame atomization typically involves a nebulizer and spray chamber assembly to combine the sample with a fuel–oxidant mixture, creating a fine aerosol mist that enters a burner. Typically, the fuel and oxidant are combined in an approximately stoichiometric ratio. However, for atoms that are easily oxidized, a fuel-rich mixture may be more advantageous. Only about 5% of the aerosol...
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Updated: Jun 16, 2026

A High Performance Impedance-based Platform for Evaporation Rate Detection
06:39

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Published on: October 17, 2016

Reactive evaporation in ionized gases.

W Heitmann

    Applied Optics
    |January 30, 2010
    PubMed
    Summary

    Ionizing residual gas significantly enhances reactivity for thin film deposition. This method yields high-quality silicon dioxide (SiO2) and titanium dioxide (TiO2) films with improved optical properties.

    Area of Science:

    • Materials Science
    • Thin Film Deposition
    • Optical Coatings

    Background:

    • Conventional reactive evaporation often results in films with non-stoichiometric compositions.
    • Non-stoichiometric films exhibit increased absorptance and dielectric losses, limiting their performance.
    • Improved deposition techniques are needed for high-quality optical films.

    Purpose of the Study:

    • To enhance the reactivity of residual gases during thin film deposition.
    • To produce high-quality silicon dioxide (SiO2), silicon oxynitride (SiOxNy), and titanium dioxide (TiO2) films.
    • To evaluate the optical properties of deposited films, specifically absorptance and refractive index.

    Main Methods:

    • Utilized a discharge tube with a high current density region for gas ionization within a bell jar.

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    Last Updated: Jun 16, 2026

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  • Introduced ionized gas directly into a high vacuum region via a nozzle.
  • Optimized production parameters for SiO2, SiOxNy, and TiO2 film deposition on unheated substrates.
  • Main Results:

    • Achieved a considerable increase in reactivity through residual gas ionization.
    • Produced SiO2 films with negligible absorptance down to 190 nm.
    • Obtained TiO2 films with high refractive indices up to 2.3.

    Conclusions:

    • Residual gas ionization is an effective method for improving thin film deposition quality.
    • The developed technique enables the production of low-loss SiO2 and high-refractive-index TiO2 films.
    • This approach offers a pathway to enhanced optical coatings with superior performance.