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Related Concept Videos

IR Spectrometers01:25

IR Spectrometers

There are two main infrared (IR) spectrophotometers: dispersive IR spectrometers and Fourier transform infrared (FTIR) spectrometers. In a dispersive IR spectrometer, a beam of infrared radiation produced by a hot wire is divided into two parallel equal-intensity beams using mirrors. One beam passes through the sample, while another is a reference beam. The beams then move through the monochromator, which separates the radiations into a continuous spectrum of different frequencies. The...
Atomic Emission Spectroscopy: Instrumentation01:22

Atomic Emission Spectroscopy: Instrumentation

The instrumentation of atomic emission spectrometry (AES) involves various components, including atomization devices that convert samples into gas-phase atoms and ions. There are two main types of atomization devices: continuous and discrete atomizers.  Continuous atomizers, like plasmas and flames, introduce samples in a constant stream, while discrete atomizers inject individual samples using syringes or autosamplers. The most common discrete atomizer is the electrothermal atomizer.
Infrared (IR) Spectroscopy: Overview01:09

Infrared (IR) Spectroscopy: Overview

When electromagnetic radiation passes through a material, atoms or molecules transition from a lower to a higher energy state by absorbing radiation corresponding to the energy difference between the two states. The absorption of infrared (IR) radiation causes transitions between vibrational energy levels in a molecule. Therefore, IR spectroscopy is a useful analytical tool for determining the molecular structure of molecules.
Different compounds display unique properties due to their...
IR Spectroscopy: Molecular Vibration Overview01:24

IR Spectroscopy: Molecular Vibration Overview

When Infrared (IR) radiation passes through a covalently bonded molecule, the bonds transition from lower to higher vibrational levels. The fundamental vibrational motions that result in infrared absorption can be classified as stretching or bending vibrations.
Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...
Atomic Emission Spectroscopy: Interference01:30

Atomic Emission Spectroscopy: Interference

In atomic emission spectroscopy (AES), high-temperature atomizers excite a broad range of elements and molecules that generate complex emissions from sources such as oxides, hydroxides, and flame combustion products in the flame or plasma. Several strategies can be employed to minimize spectral interferences caused by overlapping emission lines or bands. These include increasing instrument resolution, choosing alternative emission lines, optimally placing the detector in low-background regions,...
Raman Spectroscopy Instrumentation: Overview01:26

Raman Spectroscopy Instrumentation: Overview

A conventional Raman spectrophotometer includes a laser source, a sample holding system, a wavelength selector, and a detector.
The monochromatic laser source, typically using visible or near-infrared radiation, generates a highly focused beam of light. This light interacts with the molecules of the sample, scattering some of the light. Liquid and gaseous samples are usually tested in ordinary glass capillaries, while solids can be analyzed as powders packed in capillaries or as potassium...

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A Multimodal Wide-Field Fourier-Transform Raman Microscope
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URSIES: an Ultravariable Resolution Single Interferometer Echelle Scanner.

A A Wyller, T Fay

    Applied Optics
    |February 2, 2010
    PubMed
    Summary
    This summary is machine-generated.

    A novel instrument, URSIES, combines a Fabry-Perot interferometer and echelle monochromator for high-resolution spectroscopy. It offers variable resolution, enhanced light gain, and reduced stray light for detailed spectral analysis.

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    Area of Science:

    • Spectroscopy
    • Optical Instrumentation

    Background:

    • Traditional grating scanners face limitations in resolution and light throughput.
    • Accurate spectral analysis requires minimizing stray light and maximizing signal detection.

    Purpose of the Study:

    • To introduce and evaluate a new spectroscopic instrument, URSIES, designed for enhanced performance.
    • To demonstrate the advantages of URSIES in terms of resolution, light gain, and stray light reduction.

    Main Methods:

    • Utilized a Fabry-Perot interferometer in a Ramsay mount coupled with an echelle Hilger monochromator.
    • Employed pinholes instead of slits and enclosed the instrument in a Freon-filled pressure chamber.
    • Implemented photoelectric pulse counting and pressure scanning for spectral recording.

    Main Results:

    • Achieved a variable spectral resolution from 5.0 Å to 0.005 Å over a broad wavelength range (3500 Å to 13,000 Å).
    • Demonstrated a tenfold light gain compared to conventional grating scanners at resolutions of 0.1 Å or better.
    • Reported very low out-of-band light (<5% at 0.03 Å resolution) and minimal scattered light (<1% across 4000 Å to 11,000 Å).

    Conclusions:

    • The URSIES instrument offers significant advantages for high-resolution spectroscopy.
    • Its design enables precise spectral measurements with improved sensitivity and reduced artifacts.
    • URSIES is well-suited for applications requiring detailed analysis of light spectra, including astronomical observations.