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Improving catalytic activity by synergic effect between base and acid pairs in hierarchically porous chitosan@titania
Abdelkrim El Kadib1, Karine Molvinger, Mosto Bousmina
1Institut Charles Gerhardt, UMR 5253 CNRS/ENSCM/UM2/UM1, 8 rue de l'Ecole Normale, 34296 Montpellier Cedex 5, France. a.elkadib@inanotech.ma
Abstract:
The beneficial effect of the bifunctional character of the chitosan@titania hybrid in heterogeneous catalysis was elucidated: considering a prototypical Henry condensation, Michael addition, and Jasminaldehyde synthesis, the cohabitation of a basic site (NH(2)) and an acidic site (Ti) in the same reactor provided clear activity and selectivity enhancements, with respect to the monofunctional acidic titania and basic chitosan counterparts.
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