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Updated: Jun 16, 2026

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Anionic Polymerization of an Amphiphilic Copolymer for Preparation of Block Copolymer Micelles Stabilized by π-π Stacking Interactions
Published on: October 10, 2016
Thermally induced micelle to vesicle morphology transition for a charged chain end diblock copolymer
Adam O Moughton1, Rachel K O'Reilly
1Department of Chemistry, University of Cambridge, Cambridge, UK CB2 1EW.
Abstract:
A quaternary amine end functionalised diblock copolymer (PtBuA-b-PNIPAM) has been synthesised using RAFT polymerisation and shown to undergo a thermally induced morphology transition from micelles to vesicles, as evidenced by TEM, AFM, SLS and DLS analyses.
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