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Gas-phase water-mediated equilibrium between methylglyoxal and its geminal diol
Jessica L Axson1, Kaito Takahashi, David O De Haan
1Department of Chemistry and Biochemistry, and Cooperative Institute for Research in Environmental Sciences, Campus Box 215, University of Colorado, Boulder, CO 80309, USA.
Abstract:
In aqueous solution, aldehydes, and to a lesser extent ketones, hydrate to form geminal diols. We investigate the hydration of methylglyoxal (MG) in the gas phase, a process not previously considered to occur in water-restricted environments. In this study, we spectroscopically identified methylglyoxal diol (MGD) and obtained the gas-phase partial pressures of MG and MGD. These results, in conjunction with the relative humidity, were used to obtain the equilibrium constant, K(P), for the water-mediated hydration of MG in the gas phase. The Gibbs free energy for this process, DeltaG(o), obtained as a result, suggests a larger than expected gas-phase diol concentration. This may have significant implications for understanding the role of organics in atmospheric chemistry.
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