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Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Aryl-CF(3) bond-forming reductive elimination from palladium(IV).

Nicholas D Ball1, Jeff W Kampf, Melanie S Sanford

  • 1Department of Chemistry, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109, USA.

Journal of the American Chemical Society
|February 17, 2010
PubMed
Summary

New palladium complexes facilitate the formation of aryl-trifluoromethyl bonds through an oxidative process. This method, utilizing an electrophilic fluorinating reagent, offers a novel pathway for arene trifluoromethylation reactions.

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