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Updated: Jun 16, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Self-assembly of silver(I) metallomacrocycles using unsupported 1,4-substituted-1,2,3-triazole "click" ligands
Martin L Gower1, James D Crowley
1Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.
Abstract:
Readily synthesised mono- and di- 1,4-substituted-1,2,3-triazole "click" ligands are shown to self-assemble into discrete metallocyclic architectures with Ag(I) ions. The silver metallomacrocycles are stable in solution and the solid state and have been fully characterised by elemental analysis, HR-ESMS, IR, (1)H and (13)C NMR and in three cases the structures were confirmed by X-ray crystallography.
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