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Related Concept Videos

Photoreceptors and Visual Pathways01:22

Photoreceptors and Visual Pathways

At the molecular level, visual signals trigger transformations in photopigment molecules, resulting in changes in the photoreceptor cell's membrane potential. The photon's energy level is denoted by its wavelength, with each specific wavelength of visible light associated with a distinct color. The spectral range of visible light, classified as electromagnetic radiation, spans from 380 to 720 nm. Electromagnetic radiation wavelengths exceeding 720 nm fall under the infrared category, whereas...
UV–Vis Spectroscopy: Molecular Electronic Transitions01:16

UV–Vis Spectroscopy: Molecular Electronic Transitions

In Ultraviolet–Visible (UV–Vis) spectroscopy, the absorption of electromagnetic radiation is used to probe the electronic structure of molecules. This technique provides insights into molecular electronic transitions, particularly the movement of electrons between different molecular orbitals. Radiation is absorbed if the energy of the electromagnetic radiation passing through the molecule is precisely equal to the energy difference between the excited and ground states. During this process,...
UV–Vis Spectroscopy of Conjugated Systems01:32

UV–Vis Spectroscopy of Conjugated Systems

Organic compounds with conjugated double bonds show strong absorption features in the UV–visible region of the electromagnetic spectrum attributed to π → π* electronic excitations. Generally, a UV–vis absorption spectrum is recorded as a plot of absorbance vs wavelength. The wavelength of maximum absorbance, which manifests as a peak in the absorption spectrum, is denoted as λmax.
One of the factors influencing λmax is the extent of conjugation in the...
Photochemical Electrocyclic Reactions: Stereochemistry01:26

Photochemical Electrocyclic Reactions: Stereochemistry

The absorption of UV–visible light by conjugated systems causes the promotion of an electron from the ground state to the excited state. Consequently, photochemical electrocyclic reactions proceed via the excited-state HOMO rather than the ground-state HOMO. Since the ground- and excited-state HOMOs have different symmetries, the stereochemical outcome of electrocyclic reactions depends on the mode of activation; i.e., thermal or photochemical.
Selection Rules: Photochemical Activation
Photoelectric Effect02:26

Photoelectric Effect

When light of a particular wavelength strikes a metal surface, electrons are emitted. This is called the photoelectric effect. The minimum frequency of light that can cause such emission of electrons is called the threshold frequency, which is specific to the metal. Light with a frequency lower than the threshold frequency, even if it is of high intensity, cannot initiate the emission of electrons. However, when the frequency is higher than the threshold value, the number of electrons ejected...
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Deactivation Processes: Jablonski Diagram

Luminescence, the emission of light by a substance that has absorbed energy, is a process that involves the interaction of molecules with light. The energy-level diagram, or Jablonski diagram, is a graphical representation of these interactions, illustrating the various states and transitions a molecule can undergo. In a typical Jablonski diagram, the lowest horizontal line represents the ground-state energy of the molecule, which is usually a singlet state. This state represents the energies...

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Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
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Dynamics of photochromic conversion in optically thick samples: theory.

W J Tomlinson

    Applied Optics
    |February 19, 2010
    PubMed
    Summary

    This study introduces a new theory for optical conversion dynamics in materials of any thickness. A simplified "Photochromic Function" predicts system behavior, reducing complex calculations for researchers.

    Area of Science:

    • Physical Chemistry
    • Materials Science
    • Optics

    Background:

    • Optically induced conversion processes are crucial in various material applications.
    • Existing models often struggle with samples of arbitrary optical thickness.
    • Predicting the dynamic behavior of photochromic materials requires efficient theoretical frameworks.

    Purpose of the Study:

    • To develop a generalized theory for the dynamics of optically induced conversion processes.
    • To introduce a simplified function for predicting material state changes over time.
    • To enable efficient evaluation of photochromic system behavior without extensive computation.

    Main Methods:

    • Formulation of a first-order differential equation governing spatial state variation.
    • Development of the 'Photochromic Function' for homogeneous samples.

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  • Analysis of optical transmission measurements to determine material constants.
  • Main Results:

    • A universal theory applicable to samples of arbitrary optical thickness.
    • The Photochromic Function simplifies the prediction of dynamic behavior for homogeneous samples.
    • Identification of at most three independent material constants determinable from optical transmission.

    Conclusions:

    • The developed theory and Photochromic Function offer a powerful, computationally efficient tool for studying optically induced conversions.
    • This framework facilitates the understanding and design of photochromic materials.
    • The study provides a method to extract key material properties from experimental data.