The coordination chemistry of silyl-substituted allyl ligands

Sophia A Solomon1, Richard A Layfield

  • 1School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.

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An allyl group is a three-carbon conjugated system where the sp³-hybridized allylic carbon is bonded to a CH=CH2 group via a single bond. Allyl anions can be obtained by treating propene with a strong base that can deprotonate methyl groups. Allyl cations are formed as intermediates during substitution reactions involving allylic halides. In both cases, the hybridization of the allylic carbon changes from sp3 to sp2, giving rise to a carbon chain with three sp2-hybridized carbons, each with an...
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Isomerism in Complexes
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