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Updated: Jun 15, 2026
Close-Space Sublimation-Deposited Ultra-Thin CdSeTe/CdTe Solar Cells for Enhanced Short-Circuit Current Density and Photoluminescence
Published on: March 6, 2020
Supercrystals of CdSe quantum dots with high charge mobility and efficient electron transfer to TiO2
Elise Talgorn1, Ruben D Abellon, Patricia J Kooyman
1Optoelectronic Materials Section, Department of Chemical Engineering, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The Netherlands.
Abstract:
Thermal annealing of thin films of CdSe/CdS core/shell quantum dots induces superordering of the nanocrystals and a significant reduction of the interparticle spacing. This results in a drastic enhancement of the quantum yield for charge carrier photogeneration and the charge carrier mobility. The mobile electrons have a mobility as high as 0.1 cm(2)/(V x s), which represents an increase of 4 orders of magnitude over non-annealed QD films and exceeds existing literature data on the electron mobility in CdSe quantum dot films. The lifetime of mobile electrons is longer than that of the exciton. A fraction of the mobile electrons gets trapped at levels below the conduction band of the CdSe nanocrystals. These electrons slowly diffuse over 50-300 nm on longer times up to 20 micros and undergo transfer to a TiO2 substrate. The yield for electron injection in TiO2 from both mobile and trapped electrons is found to be >16%.
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