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Updated: Jun 15, 2026

Biosynthesis of a Flavonol from a Flavanone by Establishing a One-pot Bienzymatic Cascade
Published on: August 14, 2019
Brauhenefloroside E and F; acylated flavonol glycosides from Stocksia brauhica Linn
Viqar Uddin Ahmad1, Sadia Bader, Saima Arshad
1H. E. J. Research Institute of Chemistry, International Center for Chemical and Biological Sciences, University of Karachi, Karachi 75270, Pakistan. vuahmad@yahoo.com
Abstract:
Two new acylated flavonol glycosides, 3-O-{[2-O-beta-D-glucopyranosyl]-3-[O-beta-D-glucopyranosyl]-4-[(6-O-p-coumaroyl)-O-beta-D-glucopyranosyl]}-alpha-L-rhamnopyranosyl-kaempferol 7-O-alpha-L-rhamnopyranoside and 3-O-{2-[(6-O-p-coumaroyl)-O-beta-D-glucopyranosyl]-3-[O-beta-D-glucopyranosyl]-4-[(6-O-p-coumaroyl)-O-beta-D-glucopyranosyl]}-alpha-L-rhamnopyranosyl-kaempferol 7-O-alpha-L-rhamnopyranoside, trivially named as brauhenefloroside E (1) and F (2), respectively, were isolated from the fruits of Stocksia brauhica and their structures were elucidated using spectroscopic methods, including 2D NMR experiments.
