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Related Concept Videos

Potentiometry: Overview01:06

Potentiometry: Overview

Potentiometry is an analytical technique that measures the potential difference between two electrodes in an electrochemical cell without drawing any significant current that could alter the solution's composition. This method employs an indicator electrode, which exchanges electrons with the analyte solution, and a reference electrode with a constant potential. Each electrode is immersed in a solution comprised of two half-cells. In a conventional setup, the reference electrode serves as the...
Potentiometry: Membrane Electrodes01:15

Potentiometry: Membrane Electrodes

Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at the...
Potentiometric Titration: Overview01:31

Potentiometric Titration: Overview

Potentiometric titration is a quantitative analytical technique that determines the concentration of an analyte by measuring the potential difference between the two electrodes in the solution. The endpoint of a potentiometric titration is the point at which there is a significant change in the potential difference. It occurs when the stoichiometric reaction between the analyte and the titrant is complete. The endpoint is usually determined graphically by plotting the measured potential...
Potentiometry: Types of Electrodes01:19

Potentiometry: Types of Electrodes

Reference electrodes serve as a stable reference point for potentiometric measurements, while indicator and working electrodes react to variations in the composition of a solution.
The Standard Hydrogen Electrode (SHE) is a widely used reference electrode that maintains zero potential across all temperatures. However, its need for a continuous hydrogen gas supply renders it impractical for everyday use.
An alternative to SHE is the Saturated Calomel Electrode (SCE). This electrode features an...
Controlled-Potential Coulometry: Electrolytic Methods01:17

Controlled-Potential Coulometry: Electrolytic Methods

Controlled-potential coulometry, also known as potentiostatic coulometry, employs a three-electrode system in which the working electrode's potential is precisely regulated using a potentiostat. Platinum working electrodes are utilized for positive potentials, while mercury pool electrodes are favored for extremely negative potentials. The platinum counter electrode is separated from the analyte using a membrane or salt bridge to avoid interference in the analysis.
The chosen potential ensures...
Amperometry: Overview01:10

Amperometry: Overview

Amperometry is a technique commonly used to measure the concentration of specific analytes in a solution by monitoring the electric current generated during an electrochemical reaction. It involves applying a constant potential between a working electrode and a reference electrode to measure the resulting current, which is proportional to the concentration of the analyte. The Clark oxygen electrode operates based on this principle of amperometry. It consists of a cathode and an anode enclosed...

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Related Experiment Video

Updated: Jun 15, 2026

A Method for Systematic Electrochemical and Electrophysiological Evaluation of Neural Recording Electrodes
09:27

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Published on: March 3, 2014

Application of a potentiometric sensor array as a technique in sensory analysis.

M Hruskar1, N Major, M Krpan

  • 1Department of Food Quality Control and Nutrition, Faculty of Food Technology and Biotechnology, University of Zagreb, Pierottijeva 6, 10000 Zagreb, Croatia.

Talanta
|March 2, 2010
PubMed
Summary

An electronic tongue effectively monitored probiotic fermented milk quality during storage, classifying flavors and predicting sensory results. This sensor array offers a reliable method for assessing fermented milk characteristics.

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Published on: January 25, 2013

Area of Science:

  • Food Science and Technology
  • Analytical Chemistry
  • Sensory Science

Background:

  • Probiotic fermented milk quality is crucial for consumer acceptance.
  • Objective monitoring of sensory attributes during storage is challenging.
  • Electronic tongues offer a potential solution for rapid quality assessment.

Purpose of the Study:

  • To apply a potentiometric sensor array (electronic tongue) for monitoring probiotic fermented milk.
  • To classify probiotic fermented milk by flavor and predict human sensory panel results.
  • To assess the electronic tongue's ability to track changes during storage.

Main Methods:

  • Utilized a seven-sensor potentiometric electronic tongue with an Ag/AgCl reference electrode.
  • Monitored plain, strawberry, apple-pear, and forest-fruit probiotic fermented milk over 20 days at two temperatures.
  • Employed pattern recognition techniques: Principal Component Analysis (PCA), Artificial Neural Networks (ANN), and Partial Least Square regression (PLS).

Main Results:

  • Achieved high classification accuracy: 97% for plain and 87% for apple-pear flavored milk.
  • Demonstrated strong correlation between the electronic tongue and human sensory panel, especially for forest-fruit flavor (ANN: 0.998, PLS: 0.992).
  • Successfully monitored changes in fermented milk during storage and predicted sensory attributes.

Conclusions:

  • The potentiometric electronic tongue is a viable tool for monitoring probiotic fermented milk quality during storage.
  • It can accurately classify flavors and predict sensory characteristics, correlating well with consumer perception.
  • This technology provides an objective method to assess the quality and sensory attributes of fermented dairy products.