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Updated: Jun 15, 2026

AC Electrokinetic Phenomena Generated by Microelectrode Structures
Published on: July 28, 2008
Attraction between two similar particles in an electrolyte: effects of Stern layer absorption
Franck Plouraboué1, Hua-Chia Chang
1Centre National de la Recherche Scientifique-INPT, UMR, IMFT, UPS/No. 5502 Av. Du Professeur Camille Soula, Toulouse, France. plourab@imft.fr
Abstract:
When Debye length is comparable or larger than the distance between two identical particles, the overlapping among the particles double-layers can play an important role in their interactions. This paper presents a theoretical analysis of the interaction among two identical particles with overlapped double-layers. We particularly focus on the effect of a Stern electro static condition from linearization of the adsorption isotherm near the isoelectric (neutrality) point in order to capture how polyvalent ion condensation affect sand reverses the surface charge. The stationary potential problem is solved within the framework of an asymptotic lubrication approach for a mean-field Poisson-Boltzmann model. Both spherical and cylindrical particles are analyzed. The results are finally discussed in the context of Debye-Hückel (D-H) limit and beyond it.
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