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Related Concept Videos

Volatilization01:10

Volatilization

Volatilization gravimetry is an analytical technique that measures the mass lost due to the volatilization of the substance. This technique is used to estimate the amount of volatile material in a sample. To perform this method, heat a known amount of the sample to a high temperature in a crucible or other suitable vessel. The volatile substance in the sample evaporates, and the vapor is completely expelled from the crucible either by heating the sample or bubbling a stream of inert gas through...
Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview01:13

Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview

Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely employed in chemistry, materials science, forensic science, and other fields where sample characterization is required. ATR has several advantages over traditional transmission IR spectroscopy, including the requirement of little to no sample preparation and the ability to analyze a wide range of samples.
The ATR process begins by directing a beam...
Vapor Pressure Lowering03:28

Vapor Pressure Lowering

The equilibrium vapor pressure of a liquid is the pressure exerted by its gaseous phase when vaporization and condensation are occurring at equal rates: Dissolving a nonvolatile substance in volatile liquid results in a lowering of the liquid’s vapor pressure. This phenomenon can be explained by considering the effect of added solute molecules on the liquid's vaporization and condensation processes. To vaporize, solvent molecules must be present at the surface of the solution. The presence of...
Vapor Pressure02:34

Vapor Pressure

When a liquid vaporizes in a closed container, gas molecules cannot escape. As these gas phase molecules move randomly about, they will occasionally collide with the surface of the condensed phase, and in some cases, these collisions will result in the molecules re-entering the condensed phase. The change from the gas phase to the liquid is called condensation. When the rate of condensation becomes equal to the rate of vaporization, neither the amount of the liquid nor the amount of the vapor...
Atomic Absorption Spectroscopy: Atomization Methods01:25

Atomic Absorption Spectroscopy: Atomization Methods

Atomic Absorption Spectroscopy (AAS) atomizes samples through flame atomization or electrothermal atomization. Flame atomization typically involves a nebulizer and spray chamber assembly to combine the sample with a fuel–oxidant mixture, creating a fine aerosol mist that enters a burner. Typically, the fuel and oxidant are combined in an approximately stoichiometric ratio. However, for atoms that are easily oxidized, a fuel-rich mixture may be more advantageous. Only about 5% of the aerosol...
Vaporization01:18

Vaporization

The physical form of a substance changes by changing its temperature. For example, raising the temperature of a liquid causes the liquid to vaporize (convert into vapor). The process is called vaporization—a surface phenomenon. For vaporization to occur, kinetic energy must be greater than the intermolecular forces that keep molecules bonded. The amount of energy needed to vaporize a quantity of liquid at a given pressure and a constant temperature is called the heat of vaporization. When...

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Related Experiment Video

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Exploring the Effects of Atmospheric Forcings on Evaporation: Experimental Integration of the Atmospheric Boundary Layer and Shallow Subsurface
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Exploring the Effects of Atmospheric Forcings on Evaporation: Experimental Integration of the Atmospheric Boundary Layer and Shallow Subsurface

Published on: June 8, 2015

Water vapor differential absorption lidar development and evaluation.

E V Browell, T D Wilkerson, T J McIlrath

    Applied Optics
    |March 11, 2010
    PubMed
    Summary
    This summary is machine-generated.

    A new ground-based differential absorption lidar (DIAL) system accurately measures vertical water vapor profiles. This laser-based technology shows promise for future atmospheric research and remote sensing applications.

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    Area of Science:

    • Atmospheric Science
    • Remote Sensing
    • Optical Engineering

    Background:

    • Accurate measurement of atmospheric water vapor is crucial for weather forecasting and climate studies.
    • Traditional methods like rawinsondes have limitations in spatial and temporal resolution.
    • Differential Absorption Lidar (DIAL) offers a promising remote sensing technique for profiling water vapor.

    Purpose of the Study:

    • To describe a newly developed ground-based differential absorption lidar (DIAL) system for vertical water vapor measurements.
    • To validate the DIAL system's performance by comparing its measurements with rawinsonde data.
    • To assess the accuracy of theoretical simulations for predicting DIAL system errors.

    Main Methods:

    • Utilized a ruby-pumped dye laser system operating at a specific water vapor absorption line (724.372 nm).
    • Simultaneously transmitted ruby laser output for atmospheric scattering and attenuation characterization.
    • Employed a 0.5-m telescope and photomultiplier tubes for detecting backscattered laser light.

    Main Results:

    • The DIAL system successfully measured vertical water vapor concentration profiles at night.
    • Measurements showed agreement with rawinsonde data within the rawinsonde's uncertainty up to 3 km altitude.
    • Theoretical simulations accurately predicted the random error of the DIAL measurements.

    Conclusions:

    • The ground-based DIAL system is a reliable tool for vertical water vapor profiling.
    • Simulation results provide a strong basis for designing future airborne and spaceborne DIAL systems.
    • This technology has significant potential for advancing atmospheric research and monitoring.