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Concerto catalysis--harmonising [NiFe]hydrogenase and NiRu model catalysts

Koji Ichikawa1, Kyoshiro Nonaka, Takahiro Matsumoto

  • 1Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, 744 Moto-oka, Nishi-ku, Fukuoka 819-0395, Japan.

Dalton Transactions (Cambridge, England : 2003)
|March 12, 2010
PubMed
Summary

Researchers merged a natural nickel-iron hydrogenase (NiFe-hydrogenase) with a nickel-ruthenium mimic (NiRu-hydrogenase). This combined system enables efficient hydrogen isotope exchange reactions across a broad pH range under mild conditions.

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