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Updated: Jun 14, 2026

Synthesis of Bimetallic Pt/Sn-based Nanoparticles in Ionic Liquids
Published on: August 23, 2018
Ionic liquid immobilized nickel(0) nanoparticles as stable and highly efficient catalysts for selective hydrogenation
Yu Hu1, Yinyin Yu, Zhenshan Hou
1Key Laboratory for Advanced Materials, Research Institute of Industrial Catalysis, East China University of Science and Technology, Shanghai, 200237 China.
Abstract:
Nickel nanoparticles (NPs) well-dispersed in the aqueous phase were conveniently prepared by reducing nickel(II) salt with hydrazine in the presence of the functionalized ionic liquid 1-(3-aminopropyl)-2,3-dimethylimidazolium bromide. UV/Vis spectroscopy, elemental analysis, thermogravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS) show the presence of a weak interaction of the functionalized ionic liquid with Ni(II) and Ni(0) complexes. The face-centered cubic structure of the Ni(0) NPs was confirmed by X-ray diffraction (XRD) characterization. Transmission electron microscopy (TEM) images reveal that smaller Ni(0) particles of approximately 6-7 nm average diameter assemble to give larger, blackberry-shaped particles with an average diameter of around 35 nm. The Ni NPs were employed as highly efficient catalysts for the selective hydrogenation of C=C double bonds in the aqueous phase under mild reaction conditions (40-90 degrees C at 1.0-3.0 MPa), and the Ni(0) nanocatalysts in the aqueous phase are stable enough to be reused at least seven times without significant loss of catalytic activity during subsequent reuse cycles.
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