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Preparation of Monodomain Liquid Crystal Elastomers and Liquid Crystal Elastomer Nanocomposites
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Published on: February 6, 2016

Stimuli-responsive epoxy coatings.

Liming Tang1, John Whalen, Grant Schutte

  • 1Department of Macromolecular Science and Engineering, Case Western Reserve University, 2100 Adelbert Road, Cleveland, Ohio 44106-7202, USA.

ACS Applied Materials & Interfaces
|April 2, 2010
PubMed
Summary
This summary is machine-generated.

New epoxy coatings with built-in chemical and temperature sensors change color permanently when exposed to heat or chemicals. These smart materials offer visual detection for various stimuli.

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Area of Science:

  • Polymer Science
  • Materials Chemistry
  • Sensor Technology

Background:

  • Development of advanced materials for sensing applications is crucial.
  • Epoxy resins offer versatile matrices for incorporating functional components.
  • Chromogenic and fluorescent dyes can report on environmental changes.

Purpose of the Study:

  • To design and characterize novel epoxy coatings with integrated chemical and temperature sensors.
  • To investigate the mechanism of optical property changes in response to stimuli.
  • To explore the tunability of sensor response based on material composition.

Main Methods:

  • Synthesizing epoxy resins with dissolved oligo(p-phenylenevinylene) dye.
  • Curing polymer mixtures at high temperatures (180-200°C) and quenching.
  • Exposing materials to elevated temperatures above glass transition temperature (T(g)) and chemical stimuli.
  • Characterizing changes in optical absorption and fluorescence properties.

Main Results:

  • Kinetically trapped epoxy/dye blends exhibit irreversible dye aggregation above T(g).
  • Temperature and chemical exposure (water, acid, base, organic compounds) induce significant optical changes.
  • Changes in fluorescence and absorption spectra indicate sensor activation.
  • Response is predictable via kinetic models and controllable via resin/dye composition.

Conclusions:

  • Novel epoxy coatings function as visual chemical and temperature sensors.
  • Irreversible optical changes provide a permanent record of stimulus exposure.
  • Material design allows for tuning sensor sensitivity and response characteristics.