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Related Concept Videos

Radical Chain-Growth Polymerization: Chain Branching01:17

Radical Chain-Growth Polymerization: Chain Branching

The skeletal structure of polymers synthesized via radical polymerization is always branched. For example, the polymerization of ethylene by radical polymerization results in a low-density grade of polyethylene with a heavily branched skeletal structure. Here, the radical site abstracts hydrogen from the growing chain, and the radical site shifts from the end (a primary carbon center) to anywhere within the growing chain (a secondary carbon center). Consequently, the part of the chain from the...
Structure of Alkanes02:23

Structure of Alkanes

The formation of carbon-carbon bonds leading to the creation of the carbon chain is the basis of organic chemistry. August Kekulé and Archibald Scott Couper independently developed this idea of carbon chain formation.
Hydrocarbons are the simplest organic compounds composed of carbons and hydrogens. Based on the bond order between carbons, the hydrocarbons are further classified into alkanes, alkenes, and alkynes. 
Alkanes are the simplest hydrocarbons with sp3 hybrid carbon atoms. These sp3...
Carbon Skeletons01:12

Carbon Skeletons

Life on Earth is carbon-based, as all macromolecules that make up living organisms contain carbon atoms. All organic compounds have a carbon backbone. Each carbon atom is tetravalent and can bond with four other atoms, making it an extraordinarily flexible component of biological molecules. Because carbon’s valence electrons are stable, it rarely becomes an ion. As the carbon chain increases in length, structural modifications such as ring structures, double bonds, and branching side chains...
Ziegler–Natta Chain-Growth Polymerization: Overview01:17

Ziegler–Natta Chain-Growth Polymerization: Overview

Ziegler–Natta polymerization is another form of addition or chain‐growth polymerization used for synthesizing linear polymers over branched polymers. The catalyst used for polymerization is the Ziegler–Natta catalyst, named after Karl Ziegler and Giulio Natta, who developed it in 1953. This catalyst is an organometallic complex of titanium tetrachloride and triethyl aluminum, with the active form of the catalyst being an alkyl titanium compound. Using the Ziegler–Natta catalyst, high molecular...
Anionic Chain-Growth Polymerization: Mechanism01:04

Anionic Chain-Growth Polymerization: Mechanism

The mechanism for anionic chain-growth polymerization involves initiation, propagation, and termination steps. In the initiation step, a nucleophilic anion, such as butyl lithium, initiates the polymerization process by attacking the π bond of the vinylic monomer. As a result, a carbanion, stabilized by the electron‐withdrawing group, is generated. The resulting carbanion acts as a Michael donor in the propagation step and attacks the second vinylic monomer, which acts as a Michael acceptor.
Radical Chain-Growth Polymerization: Mechanism01:09

Radical Chain-Growth Polymerization: Mechanism

The radical chain-growth polymerization mechanism consists of three steps: initiation, propagation, and termination of polymerization. The polymerization initiates when a free radical generated from the radical initiator adds to the unsaturated bond in the monomer. The unpaired electron of the free radical and one π electron in the unsaturated bond creates a σ bond between the free radical and the monomer. As a result, the other π electron in the unsaturated bond converts this species into the...

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Related Experiment Video

Updated: Jun 14, 2026

Formation of Ordered Biomolecular Structures by the Self-assembly of Short Peptides
07:26

Formation of Ordered Biomolecular Structures by the Self-assembly of Short Peptides

Published on: November 21, 2013

Self-organized patterns in collections of chains.

T Sykes1, T Mullin

  • 1Manchester Centre for Nonlinear Dynamics, The University of Manchester, Manchester M13 9PL, United Kingdom.

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|April 7, 2010
PubMed
Summary

This study reveals critical phenomena and phase transitions in vibrated granular mixtures of poppy seeds and metal chains. Similarities to phase separation in complex fluid mixtures are observed.

Area of Science:

  • Physics
  • Materials Science
  • Complex Systems

Background:

  • Granular materials exhibit complex behaviors under external stimuli.
  • Phase separation is a fundamental phenomenon in diverse physical systems.

Purpose of the Study:

  • To investigate patterned segregation in vibrated granular mixtures.
  • To identify critical phenomena and phase transitions.
  • To compare granular system behavior with fluid mixture phase separation.

Main Methods:

  • Experimental investigation of thin layers of poppy seeds and metal chains.
  • Application of controlled vibration.
  • Mapping of a phase diagram.

Main Results:

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Last Updated: Jun 14, 2026

Formation of Ordered Biomolecular Structures by the Self-assembly of Short Peptides
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Formation of Ordered Biomolecular Structures by the Self-assembly of Short Peptides

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Synthesis of Information-bearing Peptoids and their Sequence-directed Dynamic Covalent Self-assembly

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  • Observation of both continuous and discontinuous transitions.
  • Identification of a tricritical point separating hysteretic and continuous segregation.
  • Discovery of similarities between driven granular systems and phase separation in multi-component fluids.
  • Conclusions:

    • Vibrated granular systems display critical phenomena analogous to phase separation in other complex systems.
    • The identified tricritical point is crucial for understanding segregation dynamics.
    • This research bridges the study of granular matter and soft condensed matter physics.