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Related Concept Videos

Quantifying Heat02:46

Quantifying Heat

Thermal Energy Microscopically, thermal energy is the kinetic energy associated with the random motion of atoms and molecules. Temperature is a quantitative measure of “hot” or “cold”, which depends on the amount of thermal energy. When the atoms and molecules in an object are moving or vibrating quickly, they have a higher average kinetic energy (KE) (or higher thermal energy), and the object is perceived as “hot”, or it is described as being at a higher temperature. When the atoms and...
Heat Capacities of an Ideal Gas III01:25

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The number of independent ways a gas molecule can move along straight line, rotate, and vibrate is called its degrees of freedom. Supposing d represents the number of degrees of freedom of an ideal gas, the molar heat capacity at constant volume of an ideal gas in terms of d is
Enthalpy02:59

Enthalpy

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Heat Capacities of an Ideal Gas II01:23

Heat Capacities of an Ideal Gas II

For a system that undergoes a thermodynamic process at a constant volume condition, the heat absorbed is used only to increase the system's internal energy and not for doing any kind of work. While for a system undergoing a thermodynamic process under a constant pressure condition, the amount of heat absorbed is used not only for increasing the internal energy (as a function of temperature) but also for doing some work. The molar heat capacity is the amount of heat required to increase the...
Entropy02:39

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Salt particles that have dissolved in water never spontaneously come back together in solution to reform solid particles. Moreover, a gas that has expanded in a vacuum remains dispersed and never spontaneously reassembles. The unidirectional nature of these phenomena is the result of a thermodynamic state function called entropy (S). Entropy is the measure of the extent to which the energy is dispersed throughout a system, or in other words, it is proportional to the degree of disorder of a...
Entropy01:18

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The first law of thermodynamics is quantitatively formulated via an equation relating the internal energy of a system, the heat exchanged by it, and the work done on it. A quantitative formulation of the second law of thermodynamics leads to defining a state function, the entropy.
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Related Experiment Video

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Gradient Echo Quantum Memory in Warm Atomic Vapor
10:00

Gradient Echo Quantum Memory in Warm Atomic Vapor

Published on: November 11, 2013

Dissipative quantum systems and the heat capacity.

S Dattagupta1, Jishad Kumar, S Sinha

  • 1Indian Institute of Science Education and Research-Kolkata, Mohanpur, Nadia 741252, India.

Physical Review. E, Statistical, Nonlinear, and Soft Matter Physics
|April 7, 2010
PubMed
Summary

Investigating quantum dissipative dynamics reveals distinct behaviors in specific heat at low and high temperatures. Differences emerge between Gibbs and Einstein approaches, particularly concerning confinement and cutoff frequencies.

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Area of Science:

  • Quantum mechanics
  • Statistical mechanics
  • Condensed matter physics

Background:

  • Dissipative quantum systems are crucial for understanding energy exchange and thermalization.
  • The behavior of quantum systems under dissipation is complex and depends on the chosen theoretical framework.

Purpose of the Study:

  • To analyze the quantum dissipative dynamics of a charged particle in a magnetic field.
  • To investigate the effect of dissipation on specific heat at constant volume across different temperature regimes.
  • To compare two distinct statistical mechanics approaches: Gibbs ensemble and Einstein's quantum Brownian motion.

Main Methods:

  • Exact analysis of specific heat calculations.
  • Comparison of theoretical predictions from Gibbs and Einstein methods.
  • Examination of low- and high-temperature thermodynamic behaviors.

Main Results:

  • Both Gibbs and Einstein approaches show power-law temperature dependence at low temperatures, consistent with the third law of thermodynamics.
  • High-temperature expressions align with the classical equipartition theorem.
  • Significant discrepancies arise between the two methods regarding parameter dependencies, including boundary confinement and spectral cutoff frequency.

Conclusions:

  • The choice of statistical mechanics approach significantly impacts the predicted behavior of quantum dissipative systems.
  • The influence of environmental factors like confinement and cutoff frequency is method-dependent.
  • The method of taking the asymptotic limit in the Einstein approach affects the approach to equilibrium.