Related Experiment Video
Updated: Jun 14, 2026

Excitonic Hamiltonians for Calculating Optical Absorption Spectra and Optoelectronic Properties of Molecular Aggregates and Solids
Published on: May 27, 2020
Bandlike motion and mobility saturation in organic molecular semiconductors
1Institut Néel-CNRS and Université Joseph Fourier BP 166, F-38042 Grenoble Cedex 9, France.
Abstract:
We analyze a model that accounts for the inherently large thermal lattice fluctuations associated with the weak van der Waals intermolecular bonding in crystalline organic semiconductors. In these materials the charge mobility generally exhibits a "metalliclike" power-law behavior, with no sign of thermally activated hopping characteristic of carrier self-localization, despite apparent mean free paths comparable to or lower than the intermolecular spacing. Our results show that such a puzzling transport regime can be understood from the simultaneous presence of band carriers and incoherent states that are dynamically localized by the thermal lattice disorder.
Related Concept Videos
Band Theory
The energy difference between these bands is known as the band gap.
Conductor, Semiconductor,...
Energy Bands in Solids
Band Formation:
When atoms are brought close together, as in a solid, these discrete energy levels begin to split due to the overlap of electron orbitals from adjacent atoms. This split occurs because of the Pauli exclusion principle, which states that no two...
Semiconductors
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
Molecular Orbital Theory II
π Molecular Orbitals of 1,3-Butadiene
The simplest conjugated diene is 1,3-butadiene: a four-carbon system where each carbon is sp2-hybridized and has an unhybridized p orbital that contains an unpaired electron. According to molecular orbital theory, atomic orbitals combine to form molecular orbitals such that the number...
Molecular Orbital Theory I

