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Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
Published on: June 20, 2019
High-yield synthesis of monodisperse dumbbell-shaped polymer nanoparticles
Jin-Gyu Park1, Jason D Forster, Eric R Dufresne
1Department of Mechanical Engineering, Yale University, New Haven, Connecticut 06511, USA.
Abstract:
We describe a method for producing highly monodisperse dumbbell-shaped polymer nanoparticles with dimensions on the order of a few hundred nanometers in extremely high yields. Our technique is based on seeded polymerization, where suspended core-shell particles (linear polystyrene core with polystyrene-co-trimethoxysilylpropylacrylate shell) are used as seeds. When an aqueous suspension of seed particles is mixed with monomer solution, the core-shell particles display dramatic changes in their morphology. Subsequent heating drives the polymerization of monomer, resulting in the formation of dumbbell-shaped particles. The relative sizes of the two lobes can be controlled by varying the relative volume of the monomer with respect to the seed particle. These particles are well-suited for future studies of the assembly of photonic crystals of anisotropic particles.
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