Effects of sintering temperature on physical and compositional properties of alpha-tricalcium phosphate foam

Effects of sintering temperature on the physical and compositional properties of alpha-TCP foam fabricated using the polyurethane foam method were examined. When a polyurethane foam coated with alpha-TCP slurry was sintered at 1,400-1,550 degrees C, alpha-TCP foam having basically the same fully interconnected porous structure was produced although shrinkage occurred with increasing sintering temperature. On porosity of the alpha-TCP foam, a higher foam porosity of 95% was obtained when sintered at 1,400 degrees C as compared to the 90% porosity obtained at a higher sintering temperature of 1,550 degrees C. Further, at 1,500 degrees C or higher temperature, frame became dense with disappearance of micropores. On compressive strength, it increased from approximately 50 to 250 kPa when sintering temperature was increased from 1,400 to 1,550 degrees C. Nonetheless, no compositional changes were observed even when the alpha-TCP foam was cooled in the furnace without quenching process. In light of the results obtained, it was concluded that alpha-TCP foam fabricated using the polyurethane method was useful as a bone substitute and/or scaffolding material for tissue engineering. Besides, alpha-TCP foam could be useful as a precursor for the fabrication of other calcium phosphate foams.