Electrochemical oxidation of sugars at moderate potentials catalyzed by Rh porphyrins
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Updated: Jun 14, 2026

Light-driven Enzymatic Decarboxylation
Published on: May 22, 2016
Shin-Ichi Yamazaki1, Naoko Fujiwara, Sahori Takeda
1Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST), 1-8-31 Midorigaoka, Ikeda, Osaka 563-8577, Japan. s-yamazaki@aist.go.jp
Abstract:
In this communication, we demonstrate that certain kinds of Rh porphyrins on carbon black can electrochemically oxidize aldose at low potentials. The onset potential was much lower than those with the other complex-based catalysts. A product analysis suggested that this reaction involves 2-electron oxidation of the aldehyde group.
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