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Updated: Jun 14, 2026

Evaluation of the Curing of Adhesive Systems by Rheological and Thermal Testing
Published on: July 3, 2020
Effect of curing protocol on the polymerization of dual-cured resin cements
Sónia G Pereira1, Rogério Fulgêncio, Teresa G Nunes
1Centro de Química Estrutural, IST (Instituto Superior Técnico), Av. Rovisco Pais, 1, 1049-001 Lisboa, Portugal.
Objectives:
The purpose of this study was to evaluate how curing protocol affects the extent of polymerization of dual-cured resin cements.
Methods:
Four commercial resin cements were used (DuoLink, Panavia F 2.0, Variolink II and Enforce). The extent of polymerization of the resin cements cured under different conditions was measured using a (1)H Stray-Field MRI method, which also enabled to probe molecular mobility in the kHz frequency range.
Results:
Resin cements show well distinct behaviours concerning chemical cure. Immediate photo-activation appears to be the best choice for higher filler loaded resin cements (Panavia F 2.0 and Variolink). A photo-activation delay (5 min) did not induce any significant difference in the extent of polymerization of all cements.
Significance:
The extent of polymerization of dual-cured resin cements considerably changed among products under various curing protocols. Clinicians should optimize the materials choice taking into account the curing characteristics of the cements.
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