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Updated: Jun 13, 2026

Characterizing Far-infrared Laser Emissions and the Measurement of Their Frequencies
Published on: December 18, 2015
Carbon dioxide laser absorption spectra of toxic industrial compounds
G L Loper1, G R Sasaki, M A Stamps
1The Aerospace Corporation, Chemistry & Physics Laboratory, P.O. Box 92957, Los Angeles, California 90009, USA.
Abstract:
CO(2) laser absorption cross-section data are reported for acrolein, styrene, ethyl acrylate, trichloroethylene, vinyl bromide, and vinylidene chloride. These data indicate that sub parts per billion level, interference-free detection limits should be possible for these compounds by the CO(2) laser photoacoustic technique. Photoacoustic detectabilities below 40 ppb should be possible for these compounds in the presence of ambient air concentrations of water vapor and other anticipated interferences. These compounds are also found not to be important interferences in the detection of toxic hydrazine-based rocket fuels by CO(2) laser spectroscopic techniques.
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