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Updated: Jun 13, 2026

Quantification of Hydrogen Concentrations in Surface and Interface Layers and Bulk Materials through Depth Profiling with Nuclear Reaction Analysis
Published on: March 29, 2016
Enhanced reactivity for hydrogen reactions at Pt nanoislands on Au(111)
Holger Wolfschmidt1, Daniel Weingarth, Ulrich Stimming
1Department of Physics E19, Technische Universität München, 85748 Garching, Germany.
Abstract:
We report high exchange current densities exceeding 1 A cm(-2) at Pt nanostructures on Au(111) for hydrogen-related reactions. Such activity is found at Pt nanoparticles with a coverage of less than 10 % of a monolayer on Au(111) and on single Pt particles deposited on Au(111). Potential pulse technique as well as micropolarization curves with overpotentials of +/-10 mV were used in the case of extended nanostructured surfaces to determine the activity. Single Pt particles were investigated in an in situ electrochemical scanning tunneling microscope setup using the STM tip as local sensor. The reactivity obtained on Pt nanostructured Au(111) towards hydrogen reactions were subsidized by single particle reactivity measurements. The specific activity of platinum is enhanced by more than a factor of 1000 as compared to a Pt(111) single crystal. Aspects that may explain this enhancement such as an involvement of the substrate, highly reactive defect sites and enhanced mass transport are discussed.
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