Related Experiment Video
Updated: Jan 27, 2026

Optical Trapping of Plasmonic Nanoparticles for In Situ Surface-Enhanced Raman Spectroscopy Characterizations
Published on: June 23, 2022
Optical sensors based on spectroscopy of localized surface plasmons on metallic nanoparticles: sensitivity
1Institute of Photonics and Electronics, Academy of Sciences of the Czech Republic, Chaberská 57, Prague, Czech Republic.
Abstract:
Surface plasmon resonance (SPR) sensors use two types of surface plasmons: (i) propagating along a metal-dielectric interface and (ii) localized on metallic nano-objects. This article presents theoretical analysis of sensitivity of SPR sensors based on spectroscopy of localized surface plasmons on metallic nanoparticles. Analytical formulas inter-relating bulk and surface refractive index sensitivity with main design parameters are derived using the electrostatic approximation. The effect of particle diameter is accounted for by means of Mie theory. Figures of merit for SPR sensors using localized and propagating surface plasmons are calculated and compared. Although sensors based on spectroscopy of localized surface plasmons on gold spherical particles show promise for detection of processes occurring in the close proximity of the particle surface, their performance is still inferior to that of SPR sensors based on spectroscopy of propagating surface plasmons.
More Related Videos
Related Concept Videos
Local Anesthetics: Differential Sensitivity of Nerve Fibers
Bonding in Metals
Alkali Metals
Table 1: Properties of the alkali metals
Design Consideration
The factor of safety is another key...
Metallic Solids
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...

